Hydrogen bond induced enantioselectivity in Mn(salen)-catalysed sulfoxidaton reactions.
نویسندگان
چکیده
A chiral Mn(salen) complex exhibiting two lactam binding sites at two rigid 1,5,7-trimethyl-3-azabicyclo[3.3.1]nonan-2-one skeletons is capable of enantioselective sulfoxidation due to spatially remote substrate hydrogen bonding.
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 7 شماره
صفحات -
تاریخ انتشار 2011